Apple,
Sorry, I’ve been so late in replying, it’s been pretty busy. Your question is a good one. I have always like to know the “why” behind things too.
I’m not sure I know the answer, but I’ll hazard a guess as to why the EPA has a less favorable view of organophosphates.
Generally speaking, organophosphates are more acutely toxic to mammals/humans than other classes of pesticides. As I recall, the oral LD50 for Guthion concentrate was about 50 mg/kg body weight. I looked up the LD50 for Imidan 70 and it’s 275 mg/kg. If you compare that to, say, Mustang Maxx at 310 mg/kg, it’s not a big difference.
However, that’s not the whole story. Mustang is applied at a max rate of 4 oz. per acre, whereas Imidan/phosmet is applied at a max rate of 5 lbs./acre (twenty times the amount of Mustang). So agricultural workers are probably exposed to more toxic material with Imidan than with Mustang. The same would be true with consumers eating the food. The maximum residue limit for phosmet on apples in the U.S. is 10ppm, whereas it’s only 2ppm for Zeta-cypermethrin (Mustang).
In short, even though the concentrates of Mustang and Imidan are about the same in acute toxicity, it takes much less Mustang to kill insects than it does Imidan, thereby exposing humans to much less of the compound. This is true with most pyrethroids. If you look at consumer Ready-To-Use (RTU) in home insecticides (for things like cockroaches, spiders, etc.) the active ingredient will probably be a pyrethroid and will have an amazingly small amount of the active ingredient (a very small fraction of a percentage).
Pyrethoids are not a reduced risk pesticide or classified as an “organophosphate alternative” by the EPA. Those alternatives have even higher LD50 values (some above 5000 mg/kg) making them much less toxic than organophosphates or pyrethroids.
I also suspect the long term effects of cholinesterase inhibition from too much organophosphate exposure are more problematic, but I’ve not put any effort in researching this.
All that said, I’m not trying to make a case in order to frighten people about organophosphate use. Although they are generally more toxic, Alan has frequently made a good point that past studies show applicators live longer lives (on average) than the rest of the population. These studies were conducted when organophosphate usage was in it’s heyday. That millions and millions of pounds of organophosphates were applied by thousands of applicators, and yet the applicators lived longer lives is a testament to their overall safety, when applied and used as directed.