I would mostly concur with Scott. It doesn’t look like brown rot to me, or at least I should clarify, not brown rot I’ve seen in my orchard. I’m on a commercial spray regimen, so maybe I just haven’t seen brown rot like that.
But in my own experience, and my reading, brown rot mostly affects ripening fruit, or blooms (blossom blight).
I’m not sure what I’m seeing on your green fruit.
Perhaps it is some super virulent brown rot, but I doubt it. It’s also not captan damage. I’ve sprayed captan at max rates under the worst conditions (mixing with oil, high temps, plus high humidity) and never seen fruit damaged. The leaves are the first thing you will notice on captan damage, and peach leaves are pretty tolerant of Captan.
Btw, I’m swimming up stream of the group thought on something else regarding captan. Namely, I’ve had good results with it for controlling brown rot. But… a couple caveats. First I’m spraying weekly during the wet spring. Not bi weekly, not every 10 days, but weekly. Using a sticker too.
The other thing is that I always condition the water before the captan is added. It breaks down so fast because of alkaline hydrolysis, that it can be worthless by the time you start spaying it, depending on your tap water pH.
Most spray guides rank Captan as good. Not as powerful as some of the newer chemistries. But I like it from a commercial perspective because of it’s multiple modes of action. Something a home grower wouldn’t need to be concerned with.
There are so many azoles, with single modes of action, I’m a bit glad there is something affordable out there with multiple modes of action, like Captan.